Regional seismic reflection and potential field data document the South Atlantic's break-up history, between 39°S and 19°S, from the Early Cretaceous onwards. Previous maps of distribution of volcanics along the margin showed volcanics along the whole African margin based on extrapolation of data. Based on previously unpublished marine geophysical data, we found the southernmost 460 km long margin segment to be lacking huge volumes of break-up related volcanic effusives. Northwards, break-up was accompanied by the emplacement of huge volumes of volcanic material, prominently featured in seismic sections as huge wedge-shaped seaward dipping reflectors (SDRs). Detailed mapping of offsets (left- and right-stepping) and variations in structural character of the volcanics reveal the segmentation along and the break-up history of the margin. Several superimposed SDR sequences, suggesting episodicity of volcanic emplacement (divided by periods of erosion and sedimentation), are distinct along southerly lines, losing prominence northwards. Keywords: Passive continental margin, South Atlantic, Southwest Africa, Continental break-up, Margin segmentation, Seaward Dipping Reflector Sequences (SDRs), Volcanic rifting, Sheared margin.