In a region along the western margin of the Kalahari in eastern Namibia and western Botswana, many pan basins have mainly calcareous deposits along part of their margins. These are typically lined by low vertical scarps. In Namibia, these pans are mainly located in dry river beds. The petrographical study of these deposits demonstrates that they consist of lacustrine sediments that have to a varying extent been affected by early-diagenetic processes and by the formation of late-diagenetic features. The original composition of the deposits ranges from highly calcareous sediments, typically with ostracod, diatom and charophyte remains, to entirely non-calcareous diatomites. The deposits generally show an upward increase in total carbonate content, which is mainly a synsedimentary feature. The early-diagenetic processes that affected the deposits include the formation of orthic siliceous nodules. At a later stage, secondary calcite enrichment occurred, leaving only the silica-impregnated sections unaffected. This enrichment partly accounts for the upward increase in total carbonate content in some profiles and often resulted in the development of a highly calcareous surface horizon. Sepiolite and amorphous silica that are part of the groundmass of the deposits may also partly have formed at this stage. Late-diagenetic features include various forms of secondary calcite and silica. This study of pan basins in eastern central Namibia indicates that a lacustrine rather than purely pedogenic origin should also be considered for calcareous deposits that commonly occur along pan margins in other parts of southern Africa. Keywords: lacustrine environment, carbonate sediments, diagenesis, Kalahari, Namibia.